Groundwater quality assessment in the Breede area, Western Cape, South Africa

Abstract

Groundwater is an essential part of food and water security. This critical resource must be managed appropriately and used sustainably. This study aimed to assess groundwater quality, suitability for domestic and irrigation purposes, and factors contributing to the groundwater chemistry, in the Breede Water Management Area (WMA), Western Cape, South Africa. Groundwater samples were collected and analysed for major ions such as K⁺, Mg²⁺, Na⁺, Ca²⁺, Cl^-, HCO₃^-, NO₃^-, F^-, SO₄²⁻ and physical variables like pH, electrical conductivity (EC), total dissolved solids (TDS), and temperature. Water quality index (WQI), total hardness (TH), South African Water Quality Guidelines (SAWQG) and World Health Organisation (WHO) drinking water quality guidelines were used to assess suitability for drinking purposes. Permeability index (PI), magnesium hardness (MH), sodium adsorption ratio (SAR), sodium percentage (Na%) and graphical representations such as Wilcox and United States Salinity Laboratory (USSL) diagram were used to assess suitability for irrigation purposes. Multivariate statistical analysis and the Piper diagram were used to determine the geochemical processes influencing the groundwater quality. TH and WQI revealed that, overall, groundwater in Breede WMA is soft and suitable for drinking. The irrigation suitability indices showed that groundwater is suitable for irrigation, with the exception of a few sites that are doubtful. The dominating water type in the area is Na-Cl, followed by mixed Ca-Mg-Cl. Multivariate statistical methods revealed that the groundwater is affected by the dissolution of rock salts, calcite dissolution, cation exchange and agricultural activities.  The overall groundwater in the Breede Water Management Area is suitable for domestic purposes.  Water in the boreholes along the coastal area and Borehole W1 must be treated before domestic and irrigation use. There must be consistent groundwater quality monitoring in Breede to identify changes in groundwater quality.