Catalytic wet peroxide oxidation of formic acid in wastewater with naturally-occurring iron ore
Keywords:iron ore, catalytic wet oxidation, formic acid, Fenton, hydrogen peroxide
The catalytic wet oxidation of formic acid, using hydrogen peroxide as the oxidizing agent over naturally-occurring iron ore, was explored. Firstly, the decomposition of hydrogen peroxide to its hydroxyl radicals (HO• and HOO•) over naturally-occurring iron ore was investigated. The reaction was monitored by ATR FTIR by following the disappearance of the O-H peak of H2O2 at 2 860 cm-1. Decomposition occurred according to the Fenton mechanism and resulted in observed first-order rate constants one order of magnitude faster than that without the catalyst. Turnover frequencies (TOF) of 1.97–8.85 x 10-9 s-1 were obtained for the decomposition of H2O2. The wet oxidation of formic acid using hydrogen peroxide as the oxidizing agent over naturally-occurring iron ore reaction was also monitored by ATR FTIR, following the disappearance of the carbonyl stretching frequency of formic acid at 1 727 cm-1. Experiments were performed at different hydrogen peroxide (2, 4, 6 and 8 M) and formic acid (1.26, 2.52, 6.3 and 12.6 M) concentrations as well as with varying amounts of naturally-occurring iron ore catalyst, at pH = 2. Elevated hydrogen peroxide and formic acid concentrations led to increased observed first-order kinetics, as high as kobs = 21.75 x 10-4 min-1 with a TOF = 1.73 x 10-8 – 1.12 x 10-6 s-1.
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Copyright (c) 2022 E Erasmus, JO Claassen, WA van der Westhuizen
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